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About: (1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride     Goto   Sponge   NotDistinct   Permalink

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Type: Thingdul:ChemicalObjectchemical substanceChemical compoundchemical compoundyago:WikicatCatalystsyago:WikicatCoordinationCompoundsyago:WikicatPalladiumCompoundsyago:WikicatPhosphineComplexesyago:WikicatPhosphinesyago:Abstraction100002137yago:Activator114723079yago:Catalyst114723628yago:Chemical114806838yago:Cognition100023271yago:Complex105870365yago:Complex114817592yago:Compound105870180yago:Compound114818238yago:Concept105835747yago:Content105809192yago:Fluid114939445yago:Gas114877585yago:Idea105833840yago:Material114580897yago:Matter100020827yago:Part113809207yago:Pesticide114980215yago:Phosphine114982129yago:PhysicalEntity100001930yago:PsychologicalFeature100023100yago:Relation100031921yago:Substance100019613yago:Whole105869584yago:WikicatIronCompounds New Facet based on Instances of this Class

[1,1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated as [(dppf)PdCl2]. This commercially available material can be prepared by reacting dppf with a suitable nitrile complex of palladium dichloride: dppf + PdCl2(RCN)2 → (dppf)PdCl2 + 2 RCN (RCN = CH3CN or C6H5CN) The compound is popularly used for palladium-catalyzed coupling reactions, such as the Buchwald–Hartwig amination and the reductive homocoupling of aryl halides.